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Similar to other redox signaling mechanisms such as phosphorylation, acetylation and ubiquitylation, S-nitrosation has emerged as an important redox-based post-translational modification of proteins [26,28]
In addition, storage of cysteine is one of the most important functions of GSH because cysteine is extremely unstable extracellularly and rapidly autooxidizes to cystine in a process that produces potentially toxic oxygen-free radicals [29]
What the evidence suggests: dermatological observations have noted skin-brightening effects, particularly in hyperpigmentation, melasma, and post-inflammatory darkening
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